• LATEST CHEMISTRY MCQ FOR AIIMS , NEET ,JIPMER PART - 4

    VALUABLE CHEMISTRY MCQ
    1.  Ist electron affinity (EA1 ) is positive for :
         a) O      b) F    c)   N      d) none of these

    2. N2O4 is 27 % dissociated at 308K and 1 atm pressure . The Kp would be :
        a) 0.3145 atm  b) 31.45 atm   c) 3.145 atm    d) 3145 atm

    3. The set of quantum numbers not applicable to an electron :
        a) 2 , 0 , 0 , + 1/2   b) 1 , 0 , 0 , -- 1/2    c) 1, 1, 1 , +1/2   d) 1 ,0 , 0 , + 1 /2

    4. Benzene on catalytic oxidation with air in the presence of heated V2O5  gives :
        a) malic anhydride   b) malonic acid   c) fumaric acid    d) maleic acid

    5. Calculate  the radius of anucleus of an atom having mass number  216 . Given R0 = 1.40 x10⁻¹³ cm

         a)  4.8 fermi  b) 7.8 fermi   c) 10.2 fermi   d) 8.4 fermi

    6. The lighest liquid metal is :
        a) Hg    b) Na    c) Cs   d) Fr

    7. Selenium dioxide oxidises alkynes to give :
         a) aldehyde   b) ketone   c) dialdehyde   d) diketones

    8. the half-life of radium (226 ) is 120 years. The time taken to convert 10g of radium to 1.25 g is :
        a) 120 years  b) 240 years   c) 360 years   d) 60 years

    9. Among the following the achiral amino acid is :
        a) 2 -ethylalanine   b) 2 -methylglycine  c) 2-hydroxymethyl serine d) trytopham

    10. Euchlorine is a mixture of :
          a) Cl2 and CO2    b) Cl2 and SO2    c) Cl2 and ClO2  d) none of these

    11. The bonds present in N2O5 are :
         a) covalent and ionic   b) only covalent  c) only ionic  d) covalent and coordinate

    12. Difference in density is the basis of :
          a) ultrafilteration   b) molecular attraction c) gravity separation  d) molecular seiving

    13. Which is not true about cathode rays  :
           a) A stream of electrons   b) Charged particles c) Move with speed same as that of light
           d) Can be deflected by magnetic field .

    14. Unstable substances exhibit higher radioactivity due to :
           a) low p / n ratio  b) high p / n ratio c) p / n = 1     d) none of the above

    15. The shape of gaseous SnCl2 is :
           a) angular   b) linear  c) tetrahedral   d) T-shaped

    16. In order to prepare 11 normal solution of KMnO4 , how many grams of KMnO4 are required if the solution is used in acidic medium for oxidation ?
          a) 158 g   b) 31.6 g   c) 790 g   d) 62 g

    17.  Potassium crystalizes in a bcc lattice , hence the coordination number of potassium in potassium metal
           is :
          a)  0     b) 4      c) 6      d) 8

    18.  At  STP the order of mean square velocity of molecules of H2 , N2 , O2 and HBr is :
           a) H2 > N2> O2 > HBr    b) HBr> O2 > N2 > H2   c) HBr > H2 > O2 > N2
           d) N2 > O2 > H2 > HBr

    19. For a  1 molar solution of NaCl in water at 25*C and 1 atm pressur :
          a) molarity = normality  b) molality  = normality  c) molality = mole fraction
          d) molarity  = mole fraction

    20. when two reactants A and B are mixed to give products C and D . The reaction quotient Q at the
          initial stages of the reaction :
          a) is zero   b) increase with time  c) is independent of time   d) decrease with time

    21. 0.765g of an acid gives 0.535 g of CO2 and 0.12 g of H2O . Then the ration of the percentage of
          carbon and hydrogen is  :
          a) 19 : 2   b) 18 : 11  c) 20 : 17   d)  1 : 7

    22. The pesticide DDT slowly changes to :
          a) CCl3CHO and chlorobenzene   b) p - p - dichlorodiphenylene c) p,p - dichlorodiphenyl
            dichloroethane  d) p , p - dichlorodiphenyl dichloroethene

    23. Ethanol when reacted with PCl5 gives A , POCl3 and HCl . A reacts with silver nitrite to form B (major
          product ) and AgCl . A and B are respectively :
          a) C2H5Cl   and C2H5OC2H5   b) C2H6  and C2H5OC2H5  c) C2H5Cl and C2H5NO2
          d) C2H6 and C2H5NO2

    24. The ether that undergoes electrophillic substitution reactions is :
           a) CH3OC2Hb) C2H5OCH3    c) CH3OCH3    d) C2H5OC2H5

    25. Acetophenone can be prepared by :
          a) oxidation of 1- phenylethanol    b) reaction of benzaldehyde with methyl magnesium bromide
          c) Friedel -Craft reaction of benzene with acetyl chloride
          d) Distillation of calcium benzoate
           Which of the above statements are correct ?
          a) II  and III      b) I and IV   c) I and III   d) III and IV

    26.Steel is heated to a bright red heat and then cooled slowly . It is :
         a) hardening  b) annealing  c) tempering  d) nitriding

    27. EKa - aluminium and EKa - silicon are known as :
         a) gallium and germanium  b) aluminium and silicon  c) iron and sulphur  d) proton and silicon

    28. Elements of s and p - block are called  :
          a) normal  b) representative   c) both of these   d) none of these

    29. Action of water of dilute mineral acids on metals can give :
          a) monohydrogen  b) tritium  c) dihydrogen    d) trihydrogen

    30. The degree of hardness of a sample of water containing 30 ppm of MgSO4 is :
          a) 30 ppm  b) 25 ppm  c) 20 ppm  d) 10 ppm


    31. The process of converting hydrated alumina into anhydrous alumina is called :
          a) roasting   b) smelting  c) dressing   d) calcination

    32. The Solvay process of manufacture of Na2CO3 the byproducts are :
          a) CaO , Na2CO3    b) CaCl2. CO2.NH3    c) NH4Cl. CaO    d) Na2CO3.CO2

    33. Litharge is chemically :
          a) PbO   b) PbO2    c) Pb3O4    d) Pb(CH3COO)2

    34. The pH value of ordinary water is :
          a) 7   b) 6.5   c) 5.3   d) 7.8

    35. 1000 g of calcium carbonate solution contains 10g carbonate . The concentration of solution is :
          a) 10 ppm  b) 100 ppm    c) 1000 ppm  d) 10,000 ppm

    36. Propan - 1 -ol can be prepared from propene by :
         a) H2O / H2SO4     b) Hg(OAc)2 / H2O followed by NaBH4 c) B2H6 followed by H2O2
         d) CH3CO2H / H2SO4

    37. What will be the emf for the given cell  Pt / H2 (P1 ) l H+ ( aq ) l H2 (P2 ) l Pt ?
          a) RT / F ln P1 / P2    b) RT / 2F ln P1/P2     c) RT / F ln P2 /P1  d) RT / 2F ln P2/P1

    38. Cassiterite is an ore of :
          a) Sn   b) Cu   c) Si    d) Ca

    39. Which of the following is most volatile  ?
          a) CH4    b) SiH    c) GeH4      d) SnH4

    40.  Turnbull's blue is  :
          a) ferricyanide   b) ferrous ferrocyanide   c) ferrouscyanide   d) ferriferrocyanide

    41. In the exothermic reaction the enthalpy of reaction is always  :
          a) Zero   b) positive  c) negative   d) none of these

    42. Which of the following is not considered as an organometallic compound ?
           a) Cis - platin  b) Ferrocene   c) Ziese's salt    d) Grignard reagent

    43. The normality of orthophosphoric acid having purity of 70% by weight and specific gravity 1.54 is :
          a) 11 N   b) 22 N  c) 33 N   d) 44 N

    44. Which of the following compounds exhibits stereoisomerism ?
          a) 2 methyl butene - 1  b) 3 -methyl butyne - 3    c) 3 - methyl butanoic acid
          d) 2 - methyl butanoic acid

    45. The phenomenon in which white transparent crystal changes into white powder is called :
           a) deliquescence   b) efflorescence   c) allotrophy   d) Sublimation





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